Familiar to us as the black substance in charred wood, as diamonds, and the graphite in “lead” pencils, carbon comes in several forms, or isotopes.One rare form has atoms that are 14 times as heavy as hydrogen atoms: carbon-14, or C ratio gets smaller.Dates up to this point in history are well documented for C14 calibration.For object over 4,000 years old the method becomes very unreliable for the following reason: Objects older then 4,000 years run into a problem in that there are few if any known artifacts to be used as the standard.The older an organism's remains are, the less beta radiation it emits because its C-14 is steadily dwindling at a predictable rate.So, if we measure the rate of beta decay in an organic sample, we can calculate how old the sample is. Question: Kieth and Anderson radiocarbon-dated the shell of a living freshwater mussel and obtained an age of over two thousand years.They have their work cut out for them, however, because radiocarbon (C-14) dating is one of the most reliable of all the radiometric dating methods.
Therefore it should come as no surprise that creationists at the Institute for Creation Research (ICR) have been trying desperately to discredit this method for years.
Levels of carbon-14 become difficult to measure and compare after about 50,000 years (between 8 and 9 half lives; where 1% of the original carbon-14 would remain undecayed).
The question should be whether or not carbon-14 can be used to date any artifacts at all? There are a few categories of artifacts that can be dated using carbon-14; however, they cannot be more 50,000 years old.
Libby, the discoverer of the C14 dating method, was very disappointed with this problem.
He understood that archaeological artifacts were readily available.